Dylan Secoy, 26, and Rachael Povosky, 18, were apprehended by the Raleigh County Sheriff’s Department Sunday.
Secoy is charged with murder and Povosky is charged with complicity to murder.
Both are being held in West Virginia until arrangements can be made to have them extradited back to Athens County, the Athens Police Department said.
The shooting happened Sunday at around 5 a.m. in the 100 block of W. Washington St. in Athens.
Police say they arrived to find 37-year old Floyd Victor Hart suffering from a gunshot wound. EMS was unable to save Hart, who was pronounced dead at O’Bleness Hospital.